Forces / Thermodynamics visualizer
Thermodynamics
Thermodynamics visualizer
A kinetic-theory gas box with real measured pressure from actual particle collisions, and a piston sandbox for the four classic PV processes.
The physics behind it
Formulas used in this lab
Ideal gas and kinetic theory Class 11
- Ideal gas law
- PV = nRT = NkBT
- Pressure from molecular motion
- P = (1/3)(N/V) m〈v²〉
- Average kinetic energy per molecule
- ½m〈v²〉 = (3/2)kBT
- rms speed
- vrms = √(3kBT/m) = √(3RT/M)
- Gas laws
- Boyle: PV = const (T fixed); Charles: V/T = const (P fixed); Gay-Lussac: P/T = const (V fixed)
- In the box lab
- P ∝ NT/V: more particles, a hotter gas or a smaller volume all raise the pressure
First law and the four processes Class 11
- First law
- Q = ΔU + W, W = ∫ P dV (area under the PV curve)
- Internal energy of an ideal gas
- ΔU = nCvΔT, Cp − Cv = R, γ = Cp/Cv (1.4 here)
- Isothermal (T constant)
- PV = const, ΔU = 0, W = nRT ln(V2/V1)
- Isobaric (P constant)
- V/T = const, W = PΔV
- Isochoric (V constant)
- P/T = const, W = 0, Q = ΔU
- Adiabatic (Q = 0)
- PVγ = const, TVγ−1 = const, W = (P1V1 − P2V2)/(γ − 1)
- Adiabatic vs isothermal
- the adiabatic curve is steeper on a PV diagram