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Forces / Thermodynamics visualizer

Thermodynamics

Thermodynamics visualizer

A kinetic-theory gas box with real measured pressure from actual particle collisions, and a piston sandbox for the four classic PV processes.

The physics behind it

Formulas used in this lab

Ideal gas and kinetic theory Class 11

Ideal gas law
PV = nRT = NkBT
Pressure from molecular motion
P = (1/3)(N/V) m⟨v²⟩
Average kinetic energy per molecule
½m⟨v²⟩ = (3/2)kBT
rms speed
vrms = √(3kBT/m) = √(3RT/M)
Gas laws
Boyle: PV = const (T fixed); Charles: V/T = const (P fixed); Gay-Lussac: P/T = const (V fixed)
In the box lab
P ∝ NT/V: more particles, a hotter gas or a smaller volume all raise the pressure

First law and the four processes Class 11

First law
Q = ΔU + W,  W = ∫ P dV (area under the PV curve)
Internal energy of an ideal gas
ΔU = nCvΔT,  Cp − Cv = R,  γ = Cp/Cv (1.4 here)
Isothermal (T constant)
PV = const,  ΔU = 0,  W = nRT ln(V2/V1)
Isobaric (P constant)
V/T = const,  W = PΔV
Isochoric (V constant)
P/T = const,  W = 0,  Q = ΔU
Adiabatic (Q = 0)
PVγ = const,  TVγ−1 = const,  W = (P1V1 − P2V2)/(γ − 1)
Adiabatic vs isothermal
the adiabatic curve is steeper on a PV diagram